Q. what was the capital of Ashavaka/Assaka Mahajanapada?
Answer: Potali
Notes:

The Ashavaka or Assaka mahajanapada was located on the banks of river Godavari. The capital of Ashavaka mahajanapada was Potali, that is, present-day Bodhan, district Nizamabad and some parts of Adilabad (Telangana). 

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Question Number: 38 in 11. Sixteen Mahajanapadas in above course in App.