Electronegativity is defined as an atom's ability to attract an electron pair when forming a covalent bond. This property increases as you move left to right across the periodic table due to an increase in the nuclear charge's attractive forces. It decreases as you move top to bottom, owing to the shielding effect of sub-levels and increased atomic radius, which makes electrons easier to remove. This culminates in Fluorine, being the highest and furthest to the right on the periodic table, hence it is the most electronegative.
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