IISc researchers develop self-powered UV photodetector for self-charging energy storage devices

The researchers from the Indian Institute of Science (IISc), Bengaluru have developed a cost-effective, high-performance, self-powered UV photodetector.
The self-powered UV photodetector can use the harvested optical energy for direct self-charging of energy storage devices such as supercapacitor. It can also be used for operating electronic devices in the absence of external power source.
What is Photodetector?
Photodector is a device capable of sensing (detecting) or responding to electromagnetic energy, typically light by using the electrical effect of individual photons.
What researchers have developed?

  • The researchers have developed the photodetector by integrating semiconducting vanadium doped zinc oxide (VZnO) nanoflakes with a conducting polymer.
  • The zinc oxide (ZnO) is the base material for UV detection which can be doped with vanadium to produce photodetectors that are self-powered.
  • The photodetector has superior performance in terms of faster detection of photo signals in the order of milliseconds even when UV light intensity is low.

How it works?

  • When doped with vanadium, the microstructure of ZnO changes from nanorods to closely-packed nanoflakes. It causes increase in the surface area to the volume of the material.
  • It also creates surface defects within the band gap of ZnO, which helps in trapping the UV radiation that falls on the nanoflakes.
  • These nanorods are one-dimensional and cause more light reflection from top surface. When UV light enters into pores it undergoes multiple reflections and finally gets absorbed.

What are potential benefits?

  • The nanoflake (VZnO) produces five times more photocurrent, compared with ZnO, which generates only 40 nA photocurrent.
  • Once these nanoflakes are hydrogenated, the current generation capacity further increased to 1,000 nA.
  • When these hydrogenated nanoflakes exposed to UV light, they detect photo signal within milliseconds, which is nearly 100 times faster than conventional UV photodetectors.
  • VZnO nanoflakes structure has 98% light harvesting efficiency which is much higher than 84% seen in ZnO.

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